isomerism$41077$ - определение. Что такое isomerism$41077$
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Что (кто) такое isomerism$41077$ - определение

TYPE OF STRUCTURAL ISOMERISM IN WHICH A POLYATOMIC LIGAND OR MOIETY CAN BE CONNECTED VIA DIFFERENT ATOMS
Linkage isomers; Linkage Isomerism; Linkage isomer; Ambidentate isomerism

Linkage isomerism         
In chemistry, linkage isomerism is a form of isomerism in which certain coordination compounds have the same composition but differ in their metal atom's connectivity to a ligand.
Cis–trans isomerism         
  • CIP priority]] than chlorine, so this alkene is the ''Z'' isomer
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  • ''trans''-but-2-ene
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DISTINCT ARRANGEMENTS OF SUBSTITUENTS AROUND DOUBLE BONDS IN CHEMISTRY
Cis-alkene; Z-alkene; E-alkenes; Cis stereoisomer; Cis isomer; Geometric isomer; Geometric isomers; Trans isomer; Cis-isomer; Trans-isomer; Geometric stereoisomer; Geometric stereoisomers; Geometric stereoisomerism; Cis configuration; Trans configuration; Trans-alkene; Geometrical isomer; Trans-cis isomerization; Cis/trans isomerization; Geometric isomerism; Cis-trans isomer; Cis-isomers; Cis-trans; E-isomer; Z-isomer; Geometric isomerase; Cis/trans-isomerism; Cis-conformation; Cis conformation; Cis-trans isomerism; Cis-trans isomers; Entgegen and Zusammen; Cis and Trans; E-selectivity; Trans-conformation; Cis trans; E and Z; Trans-isomers; Alkene cis effect; Cis-Trans Isomerism; Cis–trans; Double bond isomer; Trans-cis; Cis-trans isomerization; Double-bond isomerism
Cis–trans isomerism, also known as geometric isomerism or configurational isomerism, is a term used in chemistry that concerns the spatial arrangement of atoms within molecules. The prefixes "cis" and "trans" are from Latin: "this side of" and "the other side of", respectively.
Asplenia with cardiovascular anomalies         
RARE DISEASE
Ivemark Syndrome; Right Atrial Isomerism; Ivemark syndrome; Right atrial isomerism
Asplenia with cardiovascular anomalies, also known as Ivemark syndrome and right atrial isomerism, is an example of a heterotaxy syndrome. These uncommon congenital disorders are characterized by defects in the heart, spleen and paired organs such as the lungs and kidneys.

Википедия

Linkage isomerism

In chemistry, linkage isomerism or ambidentate isomerism is a form of isomerism in which certain coordination compounds have the same composition but differ in their metal atom's connectivity to a ligand.

Typical ligands that give rise to linkage isomers are:

  • thiocyanate, SCN – isothiocyanate, NCS
  • selenocyanate, SeCN – isoselenocyanate, NCSe
  • nitrite, NO2
  • sulfite, SO2−3

Examples of linkage isomers are violet-colored [(NH3)5Co-SCN]2+ and orange-colored [(NH3)5Co-NCS]2+. The isomerization of the S-bonded isomer to the N-bonded isomer occurs intramolecularly.

The complex cis-dichlorotetrakis(dimethylsulfoxide)ruthenium(II) (RuCl2(dmso)4) exhibits linkage isomerism of dimethyl sulfoxide ligands due to S- vs. O-bonding. Trans-dichlorotetrakis(dimethylsulfoxide)ruthenium(II) does not exhibit linkage isomers.